Appendix A · Finite PFC study附录 A · 有限 PFC 研究

PFC droplets in hydrogel

水凝胶中的 PFC 液滴

Finite-PFC models pass numerical checks. Target laser activation, fracture, jets and impact pressure remain unresolved.

有限 PFC 模型通过数值检验。目标激光激活、断裂、射流与冲击压力仍未解决。

Compare solved equilibrium states

比较已求解平衡状态

Select a state at stretch 2.1 and outer tension 54 mN/m. State energy does not establish an optical activation threshold.

选择伸长比 2.1、外张力 54 mN/m 的状态。状态能量无法确立光学激活阈值。

Finite PFC mass; surviving liquid shell; uniform temperature; curved phase equilibrium; infinite intact gel. Nucleation, fracture and outlets remain outside this control.

有限 PFC 质量、剩余液体壳层、均匀温度、曲面相平衡及无限完整凝胶。成核、断裂与出口仍在该对照范围之外。

PFC droplets in hydrogel: feasibility and parameter comparison

水凝胶中的 PFC 液滴:可行性与参数比较

Result: published experiments demonstrate optical cavitation of PFC droplets inside hydrogel. This study verifies a conditional finite-PFC model. Target laser threshold, channel formation, collapse jets and impact peaks are not established. Missing: the spatial models and measurements listed below.

结果:已发表实验表明,水凝胶中的 PFC 液滴可以发生光致空化。本研究验证一个有条件的有限 PFC 模型。目标样品的激光阈值、通道形成、塌缩射流和冲击峰值尚未确立。缺少:下文列出的空间模型与实测数据。

The earlier ideal-gas control calculates gel deformation and discharge through an existing outlet. Its open-gel peaks are 1.625 m/s outlet speed and 9.143 kPa elastic resistance. Its sealed control emits zero liquid. These results belong to that outlet model. PFC vaporization and fracture require additional equations.

此前的理想气体模型计算凝胶变形及已有出口中的排液。开口凝胶的峰值为出口速度 1.625 m/s、弹性阻力 9.143 kPa。密封对照的排液量为零。这些结果属于该出口模型。PFC 汽化和断裂需要额外方程。

1. Solved models and evidence

1. 已求解模型与证据

Two native COMSOL 6.4 models include finite real-fluid PFC mass, a vapor core, a surviving liquid shell and intact gel. Each retains separate inner and outer interfaces. The stationary model solves four phase, mass and traction equations. The transient uses three differential states and four thermodynamic algebraic unknowns. Native Helmholtz EOS functions are checked against independent CoolProp calculations. The transient starts from a supplied post-nucleation seed. Seed formation remains outside the solved model.

两个原生 COMSOL 6.4 模型包含有限真实流体 PFC 质量、蒸气核、剩余液体壳层和完整凝胶。内外界面分别处理。稳态模型求解四个相态、质量与牵引方程。瞬态模型包含三个微分状态及四个热力学代数未知量。原生 Helmholtz 状态方程与独立 CoolProp 计算比较。瞬态从预设的成核后种子开始。种子形成仍在已求解模型范围之外。

Question问题Current evidence现有证据Status状态
Can a PFC droplet cavitate inside gel?PFC 液滴能否在凝胶内空化?Published optical experiments in fibrin, PAAm and gelatin; PFP/PFH/PFO and several micrometre diameters纤维蛋白、PAAm 和明胶中的光学实验;PFP/PFH/PFO 及多种微米直径Feasible for published architectures [S1]已发表结构具有可行性 [S1]
Does the new finite-PFC control conserve mass and energy?有限 PFC 模型是否守恒质量和能量?60 native stationary cases and six native transients compared with independent roots/integration60 个原生稳态算例和六个原生瞬态与独立求根/积分比较Numerically verified数值验证通过
Is a stationary phase root stable?稳态相平衡根是否稳定?132 radial-branch tests plus fixed-(T,V,m) internal phase/core Hessians132 个径向分支检验及固定 (T,V,m) 的内部相态/蒸气核 Hessian 检验Constraint-specific local tests completed完成相应约束下的局部检验
What laser fluence activates this specimen?何种激光能流密度激活目标样品?Absorption, local heating, sites and activation data unavailable缺少吸收、局部加热、成核位点与激活数据Unresolved未解决
Does an intact gel open a fluid-filled path?完整凝胶能否打开充液通道?No calibrated damage or path coupling in these controls模型没有标定损伤及通道耦合Unresolved未解决
What exterior jet or impact pressure follows?会产生何种外部射流或冲击压力?No outlet, directional collapse or compressible sensor model in new controls模型没有出口、定向塌缩或可压缩传感器模型Unresolved; emitted exterior mass is exactly zero未解决;外排质量严格为零

S1: embedded-droplet experiments establish feasibility in published specimens. Their bubble model includes water vapor and noncondensable gas. These PFC models omit both. Read the complete derivation and source ledger.

S1:嵌入液滴实验确立了已发表样品中的可行性。其气泡模型含水蒸气和不凝气体。当前 PFC 模型省略两者。参阅完整推导和来源台账。

2. Parameters and comparison conditions

2. 参数与比较条件

Input输入Comparison values比较值Meaning含义
PFC speciesPFC 种类PFP; PFHGao/CoolProp 8.0.0 real-fluid EOS [S2]Gao/CoolProp 8.0.0 真实流体状态方程 [S2]
Initial radius / diameter初始半径/直径0.15, 0.3, 1.5, 3, 6 µm / 0.3, 0.6, 3, 6, 12 µmInitial LIQUID size, not initial gas size初始液态尺寸;气体种子尺寸另行定义
Shear modulus剪切模量5, 20, 100 kPaStipulated intact neo-Hookean controls; not measured target gel预设完整 neo-Hookean 对照;目标凝胶尚未实测
Effective viscosity有效黏度0, 0.01, 0.1 Pa sKelvin-Voigt controls, not target high-rate fitsKelvin–Voigt 对照;目标高速响应尚未拟合
Outer / inner tensions外/内界面张力Outer 54 mN/m; PFP inner 9.41, PFH inner 12 mN/m外界面 54 mN/m;PFP 内界面 9.41、PFH 内界面 12 mN/mRoom-temperature reference proxies held constant; PFH outer value is stipulated [S4,S5]采用恒定室温参考值;PFH 外张力为预设值 [S4,S5]
Outer-tension sensitivity外张力敏感性5, 18, 54 mN/m for PFP radius 0.3 µmPFP 半径 0.3 µm;5, 18, 54 mN/mAlternative stipulated interfaces; no coating equivalence asserted替代预设界面;涂层等效性尚未确立
Initial conditions初始条件293.15 K, ambient 100 kPa; liquid initially at ambient + outer Laplace pressure293.15 K;环境 100 kPa;初始液压为环境压力加外界面 Laplace 压力Absolute pressures, finite liquid mass绝对压力;有限液态质量
Stationary stretch稳态伸长比1.2, 1.5, 1.8, 2.1Equal-size mechanical/phase state comparisons, not laser trajectories比较同伸长比的力学/相态;激光轨迹另行求解
Transient seed瞬态种子Stretch 1.2, zero wall speed, liquid pressure 50 kPa above static host requirement伸长比 1.2;壁速为零;液压高于静态基质要求 50 kPaConditional post-nucleation state; retained seed energy calculated有条件的成核后状态;计算保留种子能量
Stopping screens停止条件First expansion turning, stretch 2.1, Mach 0.1 or 50 reference time scales首次膨胀转折、伸长比 2.1、Mach 0.1 或 50 个参考时间尺度2.1 is not measured rupture; domain exits are rejected/stopped2.1 是预设条件;越出适用域的分支停止或拒绝
Host and boundaries基质与边界Density 1000 kg/m³, sound-speed screen 1500 m/s; effectively infinite undrained host密度 1000 kg/m³;声速筛查 1500 m/s;有效无限、不排水基质No external free surface, fracture, outlet, or mass leakage无外部自由表面、断裂、出口或质量泄漏

Equal stationary stretch compares equilibrium state energies. Required state energy varies between those cases. The viscosity sweep holds retained seed energy fixed within each size. Optical design comparisons must match local incident fluence and absorption law. Mechanical comparisons must match absorbed energy and geometry. Retained seed energy includes storage and ambient work relative to the all-liquid reference. Preparation is lossless here. Measured absorption must also account for pre-seed conduction, viscosity, acoustics and water/coating heating.

同稳态伸长比比较平衡状态能量。各算例所需的状态能量不同。黏度扫描在同尺寸内固定保留种子能量。光学设计比较须匹配局部入射能流密度与吸收规律。力学比较须匹配吸收能量和几何。保留种子能量包含相对全液态参考的储能与环境功。这里假定制备无损。实测吸收还须计入成核前导热、黏性、声学及水/涂层加热。

3. Size and PFC species

3. 尺寸与 PFC 种类

At stretch 2.1, shear modulus 20 kPa and the same stipulated 54 mN/m outer interface:

条件:伸长比 2.1、剪切模量 20 kPa、预设外界面张力 54 mN/m。

PFCInitial diameter (µm)初始直径 (µm)State temperature (K)状态温度 (K)Equilibrium state energy平衡状态能量Vapor MASS fraction蒸气质量分数
PFP0.6339.7912.26 pJ20.19%
PFH0.6371.7419.61 pJ21.70%
PFP6313.785.476 nJ9.22%
PFH6342.7211.703 nJ9.60%
Finite-PFC size and species comparison有限 PFC 尺寸与种类比较
Finite-PFC size and species comparison有限 PFC 尺寸与种类比较

PFP requires lower state temperature and energy than PFH here. The 0.6 µm droplet has stronger capillary confinement. Its initial Laplace excess is 360 kPa. The 6 µm droplet has 36 kPa. Their elastic-to-capillary ratios at 20 kPa modulus are 0.111 and 1.111. Smaller droplets therefore face stronger curvature effects despite lower total energy. These temperatures describe finite-mass curved equilibrium states. Optical activation temperatures are not established.

这些对照中,PFP 的状态温度和能量低于 PFH。0.6 µm 液滴受到更强的毛细约束。其初始 Laplace 超压为 360 kPa。6 µm 液滴为 36 kPa。在 20 kPa 模量下,两者弹性/毛细比为 0.111 和 1.111。小液滴总能量较低,但曲率效应更强。这些温度描述有限质量的曲面平衡状态。光学激活温度尚未确立。

The liquid shell survives substantial expansion. At outer stretch 2.1, vapor contains about 20.2% of the smaller PFP mass. The larger case has about 9.2%. A pre-existing gas approximation removes this finite inventory constraint. Reproducing these states requires phase-specific sensible and phase energy.

显著膨胀后,液壳仍然存活。外伸长比 2.1 时,小 PFP 算例约 20.2% 的质量为蒸气。大算例约为 9.2%。预存气体近似会移除有限物质量约束。重现这些状态需要各相的显热及相变能量。

4. Gel stiffness and interface chemistry

4. 凝胶刚度与界面化学

PFP equilibria at matched stretch 2.1 and outer tension 54 mN/m:

PFP 平衡条件:同伸长比 2.1、外界面张力 54 mN/m。

Initial diameter (µm)初始直径 (µm)Shear modulus (kPa)剪切模量 (kPa)State temperature (K)状态温度 (K)State energy状态能量Elastic resistance (kPa)弹性阻力 (kPa)
0.65337.2611.57 pJ7.610
0.620339.7912.26 pJ30.438
0.6100351.4315.55 pJ152.191
65308.974.342 nJ7.610
620313.785.476 nJ30.438
6100332.7010.226 nJ152.191

Higher modulus raises gel resistance and equilibrium state energy. Modulus matters more when capillary confinement is weaker. The 20 kPa, stretch-2.1 state has 30.438 kPa elastic resistance. The earlier outlet model reaches a separate 9.143 kPa peak. Strength and fracture toughness require independent measurements.

模量越高,凝胶阻力和平衡状态能量越大。毛细约束较弱时,模量影响更明显。20 kPa、伸长比 2.1 的状态具有 30.438 kPa 弹性阻力。此前出口模型的峰值为另一状态下的 9.143 kPa。强度与断裂韧性须独立实测。

For 0.6 µm-diameter PFP at 20 kPa modulus and stretch 2.1:

条件:PFP 直径 0.6 µm、模量 20 kPa、伸长比 2.1。

Stipulated outer tension (mN/m)预设外张力 (mN/m)State temperature (K)状态温度 (K)State energy状态能量
5318.786.70 pJ
18325.428.39 pJ
54339.7912.26 pJ

Interface chemistry strongly affects the smaller droplets. Inner liquid/vapor tension sets the core pressure jump. Outer liquid/aqueous tension sets initial compression and gel traction. Use values matching interface, coating, composition and temperature. Shell disappearance requires a new gas/aqueous-gel interface and phase closure.

界面化学显著影响小液滴。内侧液/汽张力控制蒸气核压差。外侧液/水张力控制初始压缩与凝胶牵引。取值须匹配界面、涂层、组分及温度。液壳消失后,需要新的气体/水性凝胶界面规律与相态闭合。

5. Viscosity and radial expansion

5. 黏度与径向膨胀

PFP, 20 kPa shear modulus, the specified seed, and no hydraulic outlet:

条件:PFP、剪切模量 20 kPa、指定种子、无液压出口。

Initial diameter (µm)初始直径 (µm)Viscosity (Pa s)黏度 (Pa s)Retained seed energy保留种子能量Peak RADIAL speed (m/s)径向峰速 (m/s)End time (µs)结束时间 (µs)Endpoint终止条件
0.6013.50 pJ6.08880.0669stretch 2.1 screen伸长比 2.1
0.60.0113.50 pJ0.95960.3384stretch 2.1 screen伸长比 2.1
0.60.113.50 pJ0.09571.5000time window ends; unfinished growth时间窗口结束;仍在膨胀
605.857 nJ4.11320.8470stretch 2.1 screen伸长比 2.1
60.015.857 nJ2.72311.2022stretch 2.1 screen伸长比 2.1
60.15.857 nJ0.44978.5620stretch 2.1 screen伸长比 2.1
Viscosity controls黏度对照
Viscosity controls黏度对照

At 0.01 Pa s, the 0.6 µm case reaches stretch 2.1 in 0.3384 µs. Its peak radial wall speed is 0.9596 m/s. The 6 µm case reaches it in 1.2022 µs. Its peak is 2.7231 m/s. All six cases emit zero exterior mass. The small, high-viscosity case still grows at its 1.5 µs cutoff. Its maximum radius is not established beyond that window.

黏度 0.01 Pa s 时,0.6 µm 算例在 0.3384 µs 达到伸长比 2.1。其径向壁速峰值为 0.9596 m/s。6 µm 算例在 1.2022 µs 达到该值。其峰值为 2.7231 m/s。全部六个算例的外排质量为零。小尺寸高黏度算例在 1.5 µs 截止时仍在膨胀。窗口之后的最大半径尚未确立。

At 0.01 Pa s, dimensionless viscous coefficients are 3.333 and 0.333. They correspond to the smaller and larger radii. Higher viscosity slows radial growth in these matched-seed cases. An outlet adds another route for energy and fluid motion. Compare radial motion and outlet flow with their own observables.

在 0.01 Pa s 下,无量纲黏性系数为 3.333 和 0.333,分别对应小半径与大半径。匹配种子条件下,黏度增加会减慢径向膨胀。出口提供另一条能量和流体运动路径。径向运动与出口流动须分别比较各自观测量。

6. Equilibrium existence and stability

6. 平衡解与稳定性

All 132 stationary states have finite inventory and positive shell thickness. Phase densities are ordered. Both phase pressure-density slopes are positive. Every state passes the internal core/phase Hessian test at fixed temperature, volume and mass. The minimum bulk-to-capillary curvature ratio is 20.4526. Nucleation accessibility and general shape stability are not established.

全部 132 个稳态具有有限物质量和正液壳厚度。相密度顺序正确。两相的压力-密度斜率均为正。每个状态均通过固定温度、体积与质量的内部蒸气核/相态 Hessian 检验。最小体积/毛细曲率比为 20.4526。成核可达性与一般形状稳定性尚未确立。

36 closed-energy states and 94 fixed-temperature states have non-restoring radial slopes. Thermal constraints change the stability result. Halving the perturbation changes closed-energy slopes by at most 3.205e-05 relatively. No sign changes occur. Test branch stability separately from phase-root convergence.

36 个闭能量状态和 94 个定温状态具有非恢复径向斜率。热约束会改变稳定性结果。扰动减半时,闭能量斜率的最大相对变化为 3.205e-05。符号均未变化。分支稳定性须与相平衡根收敛分开检验。

Radial stability comparison径向稳定性比较
Radial stability comparison径向稳定性比较

7. Optical, fracture and depth screens

7. 光学、断裂与深度筛查

Use an illustrative local incident fluence of 20 mJ/cm² (200 J/m²). Projected-disk energies are 56.55 pJ and 5.655 nJ for 0.6 and 6 µm diameters. PFP stretch-2.1 state-energy ratios are 0.217 and 0.968. These are required effective cross-section ratios under lossless energy allocation. Effective absorption cross section divided by geometric area can exceed one. Measured absorption and activation thresholds are not established. Missing: absorber/coating heating, depth attenuation, nucleation sites and preparation losses. S7 uses different size, formulation, temperature and exposure history.

采用示例局部入射能流密度 20 mJ/cm²(200 J/m²)。0.6 和 6 µm 直径的投影圆盘能量为 56.55 pJ 和 5.655 nJ。PFP 在伸长比 2.1 的状态能量比为 0.217 和 0.968。这是假定无损分配时所需的有效截面比。有效吸收截面除以几何面积的比值可以超过一。实测吸收与激活阈值尚未确立。缺少:吸收体/涂层加热、深度衰减、成核位点与制备损失。S7使用不同尺寸、配方、温度及照射历史。

A stipulated thermal diffusivity of 1.4 × 10^-7 m²/s and 5 ns pulse gives Fourier numbers 0.00778 and 0.0000778. Heating remains spatially confined during the pulse. Uniform PFC temperature is not established. Activation requires spatial heat transfer and a nucleation-rate model. Apply equilibrium closure after a seed forms under compatible conditions.

预设热扩散率 1.4 × 10^-7 m²/s 和 5 ns 脉冲得到 Fourier 数 0.00778 与 0.0000778。脉冲期间加热局限于局部空间。PFC 温度均匀性尚未确立。激活阶段需要空间传热与成核速率模型。种子形成后,在相容条件下应用平衡闭合。

The slit-cost sweep uses covers 1/5/20/50 µm, half-widths 0.5/1/5 µm and toughnesses 0.1/1/10/100 J/m². These values define hypothetical cracks. A 20 µm cover, 0.5 µm half-width and 1 J/m² toughness costs 20 pJ. Small and large PFP seed energies are 13.50 pJ and 5.857 nJ. Under retained-seed allocation, the smaller case falls below this cost. Fracture impossibility is not established. Cooling, interface changes, prestress and other reference-energy changes alter available work. Exceeding the cost also leaves initiation and channel connectivity unresolved.

狭缝功扫描采用覆盖厚度 1/5/20/50 µm、半宽 0.5/1/5 µm、韧性 0.1/1/10/100 J/m²。这些值定义假想裂纹。20 µm 覆盖、0.5 µm 半宽及 1 J/m² 韧性的功为 20 pJ。小、大 PFP 种子能量为 13.50 pJ 与 5.857 nJ。分配保留种子能量时,小算例低于该成本。断裂不可能性尚未确立。冷却、界面变化、预应力及其他参考能量变化会改变可用功。超过该成本仍无法确定起裂与通道连通。

Fracture budget comparison断裂功预算比较
Fracture budget comparison断裂功预算比较

Finite depth requires a separate geometry check. Center-to-surface distance equals initial radius plus cover. A 3 µm radius under 1 µm cover encounters the initial surface plane at stretch 1.333. This occurs before the 2.1 screen. The infinite-host trajectory then loses its intact-interior interpretation. The CSV records standoff and this gate for every case. Finite-domain convergence remains necessary for other depths.

有限深度须单独检验几何。中心到表面的距离等于初始半径加覆盖厚度。半径 3 µm、覆盖 1 µm 的液滴在伸长比 1.333 接触初始表面平面。这早于 2.1 的筛查值。此后,无限基质轨迹不再代表完整内部膨胀。CSV 为每个算例记录距离及该门槛。其他深度仍须检验有限域收敛。

8. Models and measurements still required

8. 仍需建立的模型与测量

Stage阶段Model change模型扩展Required independent observable所需独立观测量
1. Laser and onset1. 激光与起始Spatial absorber/PFC/water/gel heat transfer; normalized optical source; metastable liquid and calibrated heterogeneous nucleation hazard吸收体/PFC/水/凝胶空间传热;归一化光源;亚稳液体与标定异质成核危险率Absorbed/local fluence and activation probability over size/fluence吸收/局部能流密度及尺寸/能流密度下的激活概率
2. Intact expansion2. 完整膨胀Finite PFC and aqueous inventories; curved interfaces and phase-transfer heat balance; finite-depth gel dynamics; shell inertia/rate rheology when needed有限 PFC 与水物质量;曲面及相变传热;有限深度凝胶动力学;必要时加入液壳惯性与速率流变Radius-time trace, displacement field, temperature/composition evidence半径-时间轨迹、位移场、温度/组分证据
3. Channel formation3. 通道形成Measured rate-dependent strength and fracture energy; cohesive/damage law; actual gap aperture, fluid filling and pressure work实测速率强度和断裂能;黏聚/损伤律;实际缝隙、充液与压力功Crack time/path/opening, ejection threshold versus cover裂纹时间/路径/开度、随覆盖厚度变化的排液阈值
4. Exterior ejection4. 外部排液Connected crack/outlet plus supplied liquid and exterior free surface; integrated mass, kinetic-energy and momentum flux连通裂纹/出口、液体供给、外部自由表面;积分质量、动能与动量通量Emitted mass, velocity history and impulse外排质量、速度历史、冲量
5. Collapse and pressure5. 塌缩与压力Nonspherical compressible multiphase calculation, actual boundary/receiver and sensor averaging非球形可压缩多相计算;实际边界/接收体和传感器平均Resolved jet movies, hydrophone trace, location/bandwidth and impulse分辨射流影像、水听器曲线、位置/带宽与冲量

The implementation plan lists boundary conditions, tolerances, calibration and held-out comparisons. Begin with one 6 µm PFP droplet and a defined free surface. Retain a 0.6 µm case to test curvature and viscosity. This sequence supports validation. An optimal size is not established. Measure absorption, high-rate gel properties, toughness, strength and depth. Couple solid damage to an actual fluid-filled path. A prescribed outlet tests discharge after connection exists.

实施计划列出边界条件、容差、标定与留出比较。先采用一个 6 µm PFP 液滴及明确自由表面。保留 0.6 µm 算例检验曲率与黏度。该顺序用于验证。最优尺寸尚未确立。须测量吸收、高速凝胶性能、韧性、强度与深度。固体损伤须耦合实际充液通道。预设出口检验连通后的排液。

9. Verification and files

9. 验证与文件

Maximum native/reference stationary relative difference is 4.516e-09. Maximum normalized transient waveform difference is 2.958e-05. Maximum native normalized energy residual is 4.971e-09. Independent DOP853/Radau and tighter-step calculations agree. Entropy drift is checked separately from the energy equation. Fresh-process reload and refinement evidence is in verification/. The prior independent review corrected seed-energy wording, fracture bounds, depth applicability, branch guards, stability scope and notation.

原生/参考稳态最大相对差为 4.516e-09。瞬态归一化波形最大差为 2.958e-05。原生归一化能量最大残差为 4.971e-09。独立 DOP853/Radau 与更小步长计算一致。熵漂移独立于能量方程检验。新进程重载和细化证据位于 verification/。此前独立审查修正了种子能量表述、断裂上界、深度适用性、分支限制、稳定性范围与符号。

The offline reader includes a computed-state selector. Download the native curved-equilibrium model and post-nucleation model. The package includes Java/Python sources, parameter and native/reference CSVs, LaTeX, the accepted English PDF and verification records. README.md gives reproduction commands.

离线阅读器包含计算状态选择器。可下载原生曲面平衡模型和成核后模型。包中包含 Java/Python 源码、参数与原生/参考 CSV、LaTeX、已接受的英文 PDF 和验证记录。README.md提供复现命令。

Status: the conditional finite-PFC comparison is complete and numerically verified. Target laser-to-fracture-to-jet validation is not established. Missing: specimen-specific spatial models and measured mechanism checks.

状态:有条件的有限 PFC 比较已完成并通过数值验证。目标激光-断裂-射流验证尚未确立。缺少:样品专属空间模型及机制实测检验。